It's a relative pressure thing.Garrobo:... But I simply cannot wrap my head around how air will compress and expand as you go up and down when it is in a metal cylinder. Guess it's old age or something.
Let's go to extremes for example.
If you take a full (3000 psi) Scuba tank down to where the water pressure outside the tank is also 3000 psi (about 6600 FSW) and open the tank valve, nothing will come out - there's no pressure difference to cause anything to flow, and the tank is "empty." If you were to put a pressure gauge on the tank, it would read "0" - gauge pressure is the difference in the pressure in the tank and the pressure outside the tank (ambient pressure). As you bring that tank up, the pressure outside the tank decreases and gas will begin to come out of the tank.
The same thing applies when at shallower depths. At 100' the total pressure is 60 psi, and a tank will read "0" when it reaches that pressure. As you ascend, the outside pressure will drop, to about 15 psi by the time you reach the surface. If you gauge it then, the tank will read 45 psi... and you'll be able to get about 1.2 CF out of it (AL 80) before it reads "0" again.
Hope that clears it up
Rick