Worth it? Short answer is, yes.
Depends on what you're hoping to achieve. If you want longer no decompression limits on your dives, it's certainly worth it. If you want to minimize your nitrogen loading, it's worth it.
As a rule of thumb, when I buy a dive package, if unlimited Nitrox for the week is under $150, or if individual fills are under $100, I take it.
$18 a bottle sounds a little high to me, unless it includes the cost of the tank rental. Also, if you're diving with the same operator who's charging you $18 a bottle for Nitrox, ask to make sure they don't arbitrarily limit your dive time to, say, 45 minutes.