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I could be wrong but I seem to remember reading that the deepest air dive ever was 332 ft. I cannot find the link or the info now though. Also the deepest tri-mix dive was over 1000 ft. With that said, I would think almost any depth on air is safe as long as one is mentally and physically prepared. Though you wont find me under 120 ft on air.
I found this article (a must read):
A Journey To 308 Metres - The Deepest Open Circuit Scuba Dive Ever @
http://www.tech-dive-academy.com/journey.html
I found this article (a must read):
A Journey To 308 Metres - The Deepest Open Circuit Scuba Dive Ever @
http://www.tech-dive-academy.com/journey.html