I don't dive doubles but I've gotten some pretty good looks at GUE doubles set ups on the boat I DM for. So take my input with a grain of salt.
If you refer to the picture below:
You'll probably want to put the second inflator hose on the left post (the one with 3 hoses already in use).
Reason for this is because your right post is already hogging an inflator hose. If you have to shut down one post you'll still want access to inflation.
So right post will have primary reg and primary inflation.
Left post will have HP, Drysuit, backup reg, and backup inflation.
If you have an argon bottle then you can simply replace the drysuit hose with your backup inflator.
I should note that crossing the inflators behind your neck would be optional in your case since you'll now have two.
You'll have to see how it plays with your long hose.
That's what makes sense to me.
Now onto the original hose setup and the reasoning for it. You want your primary and backup on different posts in case you have to shutdown one.
SPG hose goes on the left because it's more ergonomical to route your hose there. Drysuit goes on left because of ergonomics.
Inflator goes on the right because if you have a rolloff and need to inflate your BC, suddenly you'll be incapable of this. You don't want to have an unexpected loss of buoyancy control, especially when you need it. That's the mindset behind this configuration (from what I've heard).