I dive doubles (or twins as we call them) and have done since about dive #45 or so. I usually dive them no matter what sort of dive I'm doing because I don't have a STA and my wing is a doubles only wing, means if I dive a singe I have to move back to my stab jacket. This keeps everything consistient between "rec" & "tech" dives.
I agree with most of the comments here - get some experience before you start thinking about doubles, etc. The good thing about a single is it has some inbuilt "saftey" in terms of DCS. That is, usually your air consumption is so high when you start that you could not stay down long enough to get DCS even if you tried.
The only thing I really disagree with is the cost. It's really not that much more expensive! If you have the ability to do two dives a day with your current rig (ie. you own 2 cylinders so you can do 2 boat dives without having to return for refills), all you need is another 1st stage, some twinning bands, and an isolation manifold. Even if you only own 1 cylinder currently, you just need to buy a second cylinder... (and you dont even need to buy a valve, since you get that with the manifold kit).
Compare that with buying a pony - where you have to buy another cylinder, another full reg (1st and 2nd stage), spg and mounting rig. It's not a whole lot more - especially since there isn't much price difference between a 3ltr and 12ltr.