Off-gassing too quickly, in the sense you are using it, is not dangerous, but oxygen is. In addition to being a fire risk, oxygen has toxicity to the lungs and central nervous system (although breathing it one the surface, at 1 ATA, poses essentially no central nervous system risk). Brief periods of breathing O2 on the surface are probably just about harmless, but you don't have any information to allow you to know by how much you have lowered your N2 load by breathing oxygen, so it would not be wise to try to shorten surface intervals or get longer bottom times for additional dives by doing this.
In short, for a recreational diver, the biggest risk of SURFACE oxygen is the handling risk (eg. fire). The benefit is arguable, and O2 should not be used to alter the parameters of repetitive dives.