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It's a good idea but nobody checks o2 content until they get into nitrox. Very few of us also check for CO. Personally, that's exactly what I'd do, but I doubt someone diving air has the necessary equipment to do it.
Unless the tank has been sitting for 30 years with moisture in it the O2 % is fine. O2 doesn't disappear but it can be used up if oxidation is going on inside the tanks.
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