The local shop that fills my tanks insists that we check the pressure and the percent O2 before we pay for them and haul them out to the car. On tropical trips where I rent tanks, I always use the shop analyzer. Even if I blend my own (I have two blenders certificates) and I do all the calculations, I check it. On technical dives where I used 100% O2 I never checked it because I always watched them fill it from a large oxygen cylinder, clearly marked. They tend to fill those as needed, not long before the dive, so I have always had the chance to watch them fill it.
The times that I have been on a boat in the tropics where the nitrox tanks were already on the boat and they just say "pick one" I calibrate the sensor myself using the ambient air. The few times I had inconsistent readings I just assumed 34% O2 and make a profile based on that. 1.4 = (0.33)(4.12) = (0.33)(1+3.12), so 31.2 meters would be my maximum depth in that case, which is about 102 feet. I say that because in places where they push nitrox, or have "free" nitrox, the blenders are typically shooting for 32% O2, and I have seen them range from 29% to 34% using trustworthy analyzers.