There are a lot of important considerations for gas planning, but reducing deco obligation in an emergency situation is probably not the number one priority. After all, you won't survive to get to your deco stop if you tox at depth or can't validate cells.
Diluent po2 needs to be safe to breathe and also allow you to get a good verification of cells with a flush, reducing deco obligation is a smaller concern that can also be met with a safety bottle.
I'm in a similar camp as Rddvet of using a lower o2 for dilout, higher o2 for bailout. Assuming the issue is with your dil and the rebreather is still functional, having the higher o2 gas is nice for SCR mode to extend your gas supply. Having a low o2 gas for deeper dives gives you much more flexibility.
In a pinch, I don't think a 100 foot dive with 30% dil is the biggest risk, but if the cave drops down to 120 and suddenly I want to drop down there, then it starts to get dicey. If I'm going in the back of Ginnie to the point where minimizing deco obligation in an emergency is that big of a concern, then it shouldn't be a big deal to bring another safety bottle so I can stick with my lower o2 dilout. Of course, this is also why I have aluminum bailouts and steel bailouts and LP45 bailouts...get your gas well suited for your dive, including a buffer to go deeper than expected and to spend more time on deco than expected.