I have a question: What single tanks are you currently using, and if they aren't HP130s or cave-filled LP121s or some other rather large tank, why go to doubles? That's a lot of complexity, change, and burden (on land or boat) for a few extra minutes of bottom time.
Redundancy.
Also, all but the extremely minute of doubles can get you into serious deco on just about any recreational dive. For a 100-foot wreck dive using 32% I am bored and cold before I hit my NDL, and using my AL80 doubles I have over half of my backgas left when it comes time to ascend.
More gas will not get you into deco. Poor situational awareness will.
Even if you are doing shallow reef dives (20-40 ft) an HP120 or 130 will give even the hungriest of divers plenty of time to enjoy things, without the learning curve of a set of doubles. And don't forget, unless you are finding on screaming deal on a set of dubs, buying two new single tanks will be much cheaper than than buying a new set of doubles.
Peace,
Greg
It's not hard to learn how to dive with doubles and there's a myriad of reasons why someone would want to.