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Controlling one's ascent and doing some combination of stops on the way up is probably of FAR greater benefit than breathing O2.
Oxygen isn't expensive; the supply is essentially infinite, and there are many applications for it, so it's readily available. What you may have difficulty with is finding someone who will fill your bottle for you, though. Most tech diving shops will require you to present proof of Advanced Nitrox training for mixes richer than 40%.
There is no question that breathing O2 on a 15 foot stop offgases you faster than continuing to breathe backgas. The question is what the magnitude of the benefit really is. The incidence of DCS on recreational profiles where proper procedures are followed is extremely low. Controlling one's ascent and doing some combination of stops on the way up is probably of FAR greater benefit than breathing O2. Technical divers do it because it markedly shortens their decompression time, but for us recreational folks, our "deco" time is pretty minimal anyway.
The risk of breathing pure oxygen underwater is, quite simply, death. Oxygen toxicity most commonly manifests as seizures, which can occur without any premonitory symptoms. VERY few people survive seizing underwater, and only then if a savvy and very skilled buddy is IMMEDIATELY at hand. Yes, the likelihood of seizing while breathing off a hang tank at ten feet is very low, but so is the DCS risk, and DCS from a recreational dive is EXTREMELY unlikely to be lethal. You have to ask yourself, "What am I trying to accomplish?" and also, "What is the possible price I'll pay for it?" For me, O2 on recreational dives just doesn't pencil out on a risk-benefit analysis.
But how does that affect a 100% O2 deco stop bottle? I mean if pure O2 is breathed at 5m we're talking PPO2 of 1.5. Is that unsafe?
Would you take flying lesson's online? How about skydiving lessons?
If you want to use the skills and techniques from technical diving, for god's sake, take the training necessary to use them safely. Don't just take anecdotal advice from anyone on the bloody internet! Would you take flying lesson's online? How about skydiving lessons? Find a good instructor and learn to do it safely and enjoy the benefits.
rant over..........
You just need to make sure your source is sound. I wouldn't trust a web forum as my sole source of info, but a lot of this probably could be self taught with the proper resources.