Cal in air, 21%
Test against your O2 source (I have 100%). Reads 100%, you are good. Actually close to 100% is fine. Any air calibration error will be multiplied in pure O2. Depending on humidity, etc. you could actually read over 100% on pure dry O2. If just running an oxygen concentrator, you will be reading how good you are actually making O2.
When the O2 cell starts dying, the upper end of the readings is what gets chopped. You can get a reading in air, and a little richer than air, but the readings will flatten out. Once you reach where the cell is current limited (I know it makes voltage that you read, but it really makes current that is converted to voltage internal to the cell) That is when it fails. It may read air fine, 30% OK, even show 40%, but on pure O2 it may never show over 50%. This is the failure point that is so bad for CCR. If you are trying to run a set point of 1.2PPO2 and you are reading 0.50 PPO2 (50% O2 at ambient) the CCR diver, or the CCR computer, will add more O2 to try and bring the number/percent up. Ending up with a very high PPO2. Now a bad cell reading 0.50 should be easy for a trained CCR diver to see. The issue comes when they are trying to run a setpoint that is right at the current limited point. Often a CCR diver will do a spike of O2 on a dive just to make sure all the cell will read well above the normal running setpoint.
That idea of the CCR diver spiking O2 to test cells during a dive is the same as a Nitrox blender testing the analyzer on pure O2. If the analyzer will read air and 100%, it is still a good cell for reading a blend well below the 100% that it has been checked to read.