Welcome to ScubaBoard, the world's largest scuba diving community. Registration is not required to read the forums, but we encourage you to join. Joining has its benefits and enables you to participate in the discussions.
Benefits of registering include
They don't suffer CNS toxicity because even at 100%, they're only breathing 1 ATA of O2, well below the safe limit. They will suffer pulmonary effects if kept for too long on higher concentrations, which are avoided whenever possible.
What everyone else said is true, but to take it a little further....
It is my understanding that for reasons that no one understands, O2 toxicity happens in water differently than on land. When a person is on O2 under pressure in a recompression chamber, they apparently have to go much "deeper" to have the same effect that would happen on scuba.