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RumBum:I don't see why you shouldn't be able to get a Nitrox card from an online class. Of course, you should submit proof (fax/ email) that you have a valid OW card and the Nitrox card would be in the same name as the OW card.
sweatfrog:PADI took their "Discover Nitrox" & "Scuba Review" out of the online picture at the beginning of this year. Most Instructors and all of the LDS's I talk too are against online programs. For it to work, it needs to be a win, win situation for the customer, instructor and LDS.