Do you want the bottle to sling as a "pony" bottle for "oh *****" situations or do you truly want it as a stage bottle for planned/staged decompression?
What tank(s) are you diving on your back? Are you diving EANx?
Assuming you're diving at least somewhat near-recreational profiles from a depth/time standpoint, maybe with a little light deco, there's really no need to carry that much extra gas with you from a deco perspective. A 40cf bottle would have better buoyancy and slinging characteristics, and much easy to handle out of the water as well. (Assuming you're diving a single tank AL80 with EANx 32, unless you breathe like a mouse you can't really spend enough time deep enough to get into significant deco obligation.)
Similarly, if you are only looking for a redundant air source in case of emergency, a 40cf bottle would be the right choice. (Enough gas for two to ascend from 80ft, including a 3min stop.)
Of you are looking to simply carry more breathable non-deco/non-emergency gas, then you might want to consider simply getting a larger main tank. Or perhaps double AL80s? More air and potentially easier to deal with vs slinging a 40 or 80.
Last but no least, if you're thinking of slinging an AL80 simply because you have ready access to an AL80, that's cool. Depending on which tank you have the buoyancy and trim characteristics are pretty benign once in the water.