When I first started diving doubles, I was diving wet and chose to double up 2 AL 80's.
Steel cylinders would have been too heavy with no redundant bouyancy.
If you were to double them up, my suggestion would be to find two cylinders that are REALLY close in serial number from the same manufacturer. Your LDS may purchase their cylinders in lots which will give you a better chance of finding two VERY similar cylinders.
All cylinders are not created equal. The manufacturing process allows discrepencies within certain defined limits that could make it difficult to match cylinders.
Catalina cylinders permits a certain amount of "bowing" to the cylinder. Banana shape if you will. It does not affect the "quality or usability" of the cylinder, but will make it difficult to double up.
Luxfer has similar specifications, as does all steel manufacturers.
As for color and boots, I have two different color cylinders...which always helps my buddies find me at depth and I do not use boots on any of my doubles.
As for the weight swing...that you will experience with steel or aluminum...I use an 8 lb. V weight that I made similar to the ones that Dive Rite sells that fits between the bolts on the bands.
Good luck,
Hope this helps.
C_C