you're pretty limited with the S400
Using the Function/Erase button you'd have to poke around in the menus and can set the following things that will affect shutter speed:
# Long Shutter: Accesses longer shutter times, from one to 15 seconds. (Only appears as a submenu to Exposure Compensation when the feature has been enabled in the Record menu.)
# ISO Speed: Sets the camera's sensitivity to Auto, or to 50, 100, 200, or 400 ISO equivalents.
So really the setting is just for "slow" shutter speeds.
So assuming you're wanting "fast" shutter speeds, I believe you're really limited to setting the ISO which could speed it up (but the camera works out the apperture and shutter speed for you)
in good light you'll be able to attain higher shuter speeds with the same ISO, otherwise make the ISO a bigger number (more sensitive to light, but the downside is more noise.)
... play a bit taking the same photo in the same light with the various ISO settings and see how the shutter speed changes (and how much noise is generated) ... bottom line is this camera is really an older point and shoot ... next time you upgrade, make sure there are some manual functions

[or just use it as a point and shoot]