The question is not entirely clear to me, but reminds me of one I asked as a new diver.
There is a certain partial pressure of CO2 in inspired air on land, although it is very low. It might become significant when compressed and breathed under pressure, if it weren't for the fact that the filter systems on dive shop compressors scrub all the CO2 out of the air that's pumped into your tank.
CO2 eliminate, in the absence of inspired CO2, is completely determined by total minute ventilation (volume, not mass) put through the lungs. As you observe, if the same volume is breathed at 100 feet as at sea level, CO2 ought to remain normal.
However, three things change at depth. One is that the air you are breathing is denser. This creates turbulent flow in the smaller airways, which results in more resistance and less EFFECTIVE ventilation of the alveoli, or air sacs, where gas exchange occurs. Secondly, dense gas is harder to pull through a regulator, resulting in increased work of breathing. We are not used to this -- breathing on land is all but effortless -- and increased work of breathing quickly results in ineffective CO2 elimination. Which brings us to the final point, which is that, for some unknown reason, some people seem to tolerate elevated CO2 levels when diving, whereas almost no one with normal lungs tolerates them on land. (In fact, the inability to normalize CO2 generally makes people VERY anxious.) The bottom line is that elevated CO2 levels are easy to achieve and frequently reasonably tolerated while diving -- but it doesn't take much of an elevation above where you are tolerant to cause a high anxiety state.